SCHEDULED MAINTENANCE
The synthesis of derivatives of sisosamine (12) and purpurosamine C (16), components of the amino-glycoside antibiotics, sisomicin (1) and gentamicin C1a(2) is described; one key intermediate, 2-azido-2,3-dideoxy-6-O-toluene-p-sulphonyl-α-D-erythro-hexopyranosid-4-ulose (5) being used for both reaction sequences.
J. Cleophax, S. D. Gero, E. Jegou-Aumont, J. Leboul, D. Mercier and A. Forchioni, J. Chem. Soc., Chem. Commun., 1975, 11 DOI: 10.1039/C39750000011
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