Issue 10, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

Redistribution reactions of organometallic complexes: carbonyl, halogen, and phosphine ligand exchange between co-ordinately unsaturated rhodium(I) and iridium(I) complexes

Philip E. Garrou  and  George E. Hartwell  

Abstract

Intermolecular redistribution of carbonyl, halide, and phosphine ligands is found to occur in systems of the type M(CO)X(PR3)2(M = Rh, Ir; X = Cl, Br); carbonyl and halogen exchanges is propesed to occur through doubly five-co-ordinate bridged intermediates.

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Article information

DOI
https://doi.org/10.1039/C39740000381
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 381-382

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Redistribution reactions of organometallic complexes: carbonyl, halogen, and phosphine ligand exchange between co-ordinately unsaturated rhodium(I) and iridium(I) complexes

P. E. Garrou and G. E. Hartwell, J. Chem. Soc., Chem. Commun., 1974, 381 DOI: 10.1039/C39740000381

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