Issue 12, 1973
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel cleavage of phosphinoacetylene by palladium(II) and platinum(II): preparation and structure of complexes of 1,3-bis(diphenylphosphino)-2-tri-fluoromethylpropene derived from 3,3,3-trifluoropropynyldiphenylphosphine

Richard T. Simpson,   Stephen Jacobson,   Arthur J. Carty,   Mathai Mathew  and  Gus J. Palenik  

Abstract

Unsymmetrical ditertiary phosphine complexes [Ph2PCH2C(CF3)[double bond, length as m-dash]CHPPh2]–MX2(M = Pd or Pt and X = Cl or SCN) have been prepared by reaction of Ph2PC[triple bond, length half m-dash]CCF3 with MX42– salts and characterized by an X-ray study of the Pd(SCN)2 derivatives.

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Article information

DOI
https://doi.org/10.1039/C39730000388
Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 388-389

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Novel cleavage of phosphinoacetylene by palladium(II) and platinum(II): preparation and structure of complexes of 1,3-bis(diphenylphosphino)-2-tri-fluoromethylpropene derived from 3,3,3-trifluoropropynyldiphenylphosphine

R. T. Simpson, S. Jacobson, A. J. Carty, M. Mathew and G. J. Palenik, J. Chem. Soc., Chem. Commun., 1973, 388 DOI: 10.1039/C39730000388

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