Issue 22, 1972

Gas-phase conformational preference of the methyl group from equilibration of 1-, 3-, and 4-methyldiamantane on a chlorinated platinum–alumina catalyst

Abstract

On a chlorinated platinum–alumina catalyst/hydrogen chloride co-catalyst, the isomeric methyldi-amantanes establish equilibrium, the temperature dependence of which yields a value of 2·14 kcal mol–1 for the gas-phase conformational ethalpy of the methyl group.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 1209-1210

Gas-phase conformational preference of the methyl group from equilibration of 1-, 3-, and 4-methyldiamantane on a chlorinated platinum–alumina catalyst

R. Hamilton, D. E. Johnston, M. A. McKervey and J. J. Rooney, J. Chem. Soc., Chem. Commun., 1972, 1209 DOI: 10.1039/C39720001209

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