A semi-theoretical expression for the “α-effect” is derived and applied to the reactions of oximate, hydroxamate, and peroxide ions with benzyl halides and p-nitrophenyl acetate, and of a series of heterocyclic molecules with 2,4-dinitrophenyl acetate.
F. Filippini and R. F. Hudson, J. Chem. Soc., Chem. Commun., 1972, 522 DOI: 10.1039/C39720000522
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