Issue 20, 1971

Methyltrineopentyloxyphosphonium iodide: a crystalline Michaelis-Arbuzov intermediate and its mode of decomposition

Abstract

Methyltrineopentyloxyphosphonium iodide is obtained as a stable, crystalline intermediate, by the interaction of trineopentyl phosphite and iodomethane at room temperature; in solution the intermediate decomposes by a first-order reaction to yield neopentyl iodide, without rearrangement.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 1297-1297

Methyltrineopentyloxyphosphonium iodide: a crystalline Michaelis-Arbuzov intermediate and its mode of decomposition

H. R. Hudson, R. G. Rees and J. E. Weekes, J. Chem. Soc. D, 1971, 1297 DOI: 10.1039/C29710001297

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