SCHEDULED MAINTENANCE
Perfluorobicyclo[2,2,0]hex-2-ene (1) is a reactive dienophile and substitution of the vinylic fluorine atoms in (1) by hydrogen to give (3) increases the dienophilic reactivity towards furan; however, the dimethyl-, monomethoxy-, and dimethoxy-derivatives (2), (6), and (4) display no dienophilic reactivity towards furan.
W. J. Feast, W. K. R. Musgrave and R. G. Weston, J. Chem. Soc. D, 1971, 709 DOI: 10.1039/C29710000709
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