Secondary ions, Mm(CO)n+, considered to arise from ion–molecule reactions, have been observed in the mass spectra of Cr(CO)6, Mo(CO)6, and W(CO)6 at 10–5–10–6 Torr at 35–100°; depending upon m(1–3 for Cr, 1–2 for Mo, and 1–4 for W) the value of n is 0–14.
C. S. Kraihanzel, J. J. Conville and J. E. Sturm, J. Chem. Soc. D, 1971, 159 DOI: 10.1039/C29710000159
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