SCHEDULED MAINTENANCE
RhCl(salen)(py) is reduced by sodium amalgam or NaBH4 in alkaline solution to give compounds which react with alkyl halides to yield the alkyls RhR(salen)(py)(R = Me or Et); reduction of the chloro-complex with zinc amalgam gives a compound believed to be the metal–metal-bonded dimer [Rh(salen)(py)]2.
R. J. Cozens, K. S. Murray and B. O. West, J. Chem. Soc. D, 1970, 1262 DOI: 10.1039/C29700001262
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