Issue 19, 1970

Asymmetric isomerization of racemic α-olefins by titanium tetra-(–)-menthoxide–tri-isobutylaluminium

Abstract

The homogeneous catalytic system obtained from AlBu3i and an optically active titanium alkoxide [titanium tetra-(–)-menthoxide] effects asymmetric isomerization of racemic α-olefins into Z- and E-2-olefins, whereas no asymmetric transformation occurs in the hydrogenation.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 1260-1261

Asymmetric isomerization of racemic α-olefins by titanium tetra-(–)-menthoxide–tri-isobutylaluminium

C. Carlini, D. Politi and F. Ciardelli, J. Chem. Soc. D, 1970, 1260 DOI: 10.1039/C29700001260

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