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Issue 13, 2015
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Covalent anchoring of multifunctionized gold nanoparticles on electrodes towards an electrochemical sensor for the detection of cadmium ions

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Abstract

This paper reports an electrochemical sensor based on the covalent anchoring of aryldiazonium salt modified AuNPs to gold electrodes for the sensitive detection of cadmium ions (Cd2+). AuNPs modified with 4-nitrophenyl and 4-carboxylphenyl were first prepared, which were then immobilized in situ on gold electrodes to achieve Au–Ph–AuNP modified interfaces. Glutathione (GSH) was finally modified to Au–Ph–AuNP by amide bonding to achieve an Au–Ph–AuNP–GSH sensing interface, which was used to detect Cd2+ over the concentration range from 0.1 nM to 100 nM with a detection limit of 0.1 nM. This electrochemical sensor demonstrated high stability and sensitivity to Cd2+. It has potential use in an in situ anchoring AuNP strategy to fabricate portable devices for the onsite monitoring of trace amounts of heavy metals.

Graphical abstract: Covalent anchoring of multifunctionized gold nanoparticles on electrodes towards an electrochemical sensor for the detection of cadmium ions

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Publication details

The article was received on 21 May 2015, accepted on 01 Jun 2015 and first published on 01 Jun 2015


Article type: Paper
DOI: 10.1039/C5AY01324K
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Anal. Methods, 2015,7, 5619-5626

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    Covalent anchoring of multifunctionized gold nanoparticles on electrodes towards an electrochemical sensor for the detection of cadmium ions

    G. Liu, Y. Zhang, M. Qi and F. Chen, Anal. Methods, 2015, 7, 5619
    DOI: 10.1039/C5AY01324K

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