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Issue 9, 2015
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High chemiluminescence activity of an FeIII–TAML activator in aqueous–organic media and its use in the determination of organic peroxides

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Abstract

High activity of FeIII–TAML, peroxidase mimic, upon the catalytic oxidation of luminol in aqueous–organic media (ethanol, isopropanol and acetonitrile) was determined. Using FeIII–TAML the sensitive chemiluminescence assays for the determination of benzoyl peroxide and tert-butyl hydroperoxide in the presence of organic solvents were performed.

Graphical abstract: High chemiluminescence activity of an FeIII–TAML activator in aqueous–organic media and its use in the determination of organic peroxides

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Article information


Submitted
24 Oct 2014
Accepted
12 Mar 2015
First published
12 Mar 2015

Analyst, 2015,140, 2964-2968
Article type
Communication
Author version available

High chemiluminescence activity of an FeIII–TAML activator in aqueous–organic media and its use in the determination of organic peroxides

A. S. Demiyanova and I. Yu. Sakharov, Analyst, 2015, 140, 2964
DOI: 10.1039/C4AN01943A

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