Issue 9, 2015
From the journal:

Analyst

High chemiluminescence activity of an FeIII–TAML activator in aqueous–organic media and its use in the determination of organic peroxides†

Alexandra S. Demiyanovaa  and  Ivan Yu. Sakharov*a  

* Corresponding authors

a Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia
E-mail: sakharovivan@gmail.com
Fax: +7 (495)9395417
Tel: +7 (495) 9393407

Abstract

High activity of FeIII–TAML, peroxidase mimic, upon the catalytic oxidation of luminol in aqueous–organic media (ethanol, isopropanol and acetonitrile) was determined. Using FeIII–TAML the sensitive chemiluminescence assays for the determination of benzoyl peroxide and tert-butyl hydroperoxide in the presence of organic solvents were performed.

Graphical abstract: High chemiluminescence activity of an FeIII–TAML activator in aqueous–organic media and its use in the determination of organic peroxides

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Article information

DOI
https://doi.org/10.1039/C4AN01943A
Article type
Communication
Submitted
24 Oct 2014
Accepted
12 Mar 2015
First published
12 Mar 2015

Analyst, 2015,140, 2964-2968

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High chemiluminescence activity of an FeIII–TAML activator in aqueous–organic media and its use in the determination of organic peroxides

A. S. Demiyanova and I. Yu. Sakharov, Analyst, 2015, 140, 2964 DOI: 10.1039/C4AN01943A

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