Issue 20, 2011
From the journal:

Analyst

A new solvent polymeric membrane electrode incorporating poly(N-isopropylacrylamide) as a polymer†

Takayo Moriuchi-Kawakami,*a   Hiroyuki Kurikawa,a   Hiroya Matsumotoa  and  Yasuhiko Shibutania  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi, Osaka, Japan
E-mail: kawakami@chem.oit.ac.jp
Fax: +81 6 6957 2135
Tel: +81 6 6954 4281

Abstract

Here, we report on a new solvent polymeric membrane electrode incorporating thermoresponsive poly(N-isopropylacrylamide) (PIPA) as a polymer with the lower critical solution temperature (LCST) of ca. 32 °C. The response of the solvent polymeric membrane electrode to the ions changes at 25 and 40 °C. Pulsed NMR analyses demonstrated the novel effects of the LCST behaviour on the potentiometric polymeric membrane.

Graphical abstract: A new solvent polymeric membrane electrode incorporating poly(N-isopropylacrylamide) as a polymer

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Article information

DOI
https://doi.org/10.1039/C1AN15306D
Article type
Communication
Submitted
13 Apr 2011
Accepted
27 Jul 2011
First published
26 Aug 2011

Analyst, 2011,136, 4141-4143

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A new solvent polymeric membrane electrode incorporating poly(N-isopropylacrylamide) as a polymer

T. Moriuchi-Kawakami, H. Kurikawa, H. Matsumoto and Y. Shibutani, Analyst, 2011, 136, 4141 DOI: 10.1039/C1AN15306D

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