Issue 12, 2009
From the journal:

Analyst

Chemiluminescence from the reaction of tin(ii) with tris(2,2′-bipyridyl)ruthenium(iii)

Michelle E. Gange,a   Simon C. Parratt,b   Philip Jones,c   Paul S. Francisa  and  Neil W. Barnett*a  

* Corresponding authors

a School of Life and Environmental Sciences, Deakin University, Geelong, Victoria 3217, Australia
E-mail: barnie@deakin.edu.au
Fax: +61 3 5227 1040
Tel: +61 3 5227 1409

b Kardinia International College, Geelong, Victoria 3220, Australia

c Department of Environmental Science, University of Plymouth, Plymouth, Devon, UK

Abstract

Unlike many other metal and metalloid ions, tin(II) elicits intense, analytically useful chemiluminescence upon reaction with tris(2,2′-bipyridyl)ruthenium(III) in acidic aqueous solution. This finding provides new insight into the nature of this widely used reagent and has enabled the first direct, selective determination of a metal ion with tris(2,2′-bipyridyl)ruthenium(III).

Graphical abstract: Chemiluminescence from the reaction of tin(ii) with tris(2,2′-bipyridyl)ruthenium(iii)

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Article information

DOI
https://doi.org/10.1039/B918641G
Article type
Communication
Submitted
10 Sep 2009
Accepted
16 Oct 2009
First published
27 Oct 2009

Analyst, 2009,134, 2397-2399

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Chemiluminescence from the reaction of tin(II) with tris(2,2′-bipyridyl)ruthenium(III)

M. E. Gange, S. C. Parratt, P. Jones, P. S. Francis and N. W. Barnett, Analyst, 2009, 134, 2397 DOI: 10.1039/B918641G

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