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Issue 7, 2009
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Chemiluminescence from reactions with bis-cyclometalated iridium complexes in acidic aqueous solution

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Abstract

Chemical reactions between certain bis-cyclometalated iridium complexes, cerium(IV) and organic reducing agents in aqueous solution produce an emission of light which in some cases is more intense than that from analogous reactions with conventional ruthenium-based reagents, thus providing a new avenue for chemically-initiated luminescence detection.

Graphical abstract: Chemiluminescence from reactions with bis-cyclometalated iridium complexes in acidic aqueous solution

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Article information


Submitted
11 Mar 2009
Accepted
14 Apr 2009
First published
21 Apr 2009

Analyst, 2009,134, 1297-1298
Article type
Communication

Chemiluminescence from reactions with bis-cyclometalated iridium complexes in acidic aqueous solution

R. V. Kiran, E. M. Zammit, C. F. Hogan, B. D. James, N. W. Barnett and P. S. Francis, Analyst, 2009, 134, 1297
DOI: 10.1039/B905024H

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