A metal–metal quadruply bonded dimer of two pincer-ligated metal centers
Abstract
Reduction of the pincer complex (PArNP)MoBr3 using Na/Hg under argon yields a quadruply bonded Mo–Mo dimer, (κ3-PArNP)BrMo
Mo(κ3-PArNP)Br. The complex represents a rare example of a metal–metal bonded species in which both metal centers bear a κ3-mer coordinated pincer ligand.

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