Bimetallic nanoparticles as pioneering eco-friendly catalysts for remediation of pharmaceuticals and personal care products (PPCPs)

Abstract

The persistent presence of Pharmaceuticals and Personal Care Products (PPCPs) in aquatic environments poses a significant risk to both human health and ecosystems, with conventional water treatment methods often unable to effectively remove these contaminants. Recent research has identified bimetallic nanoparticles as a promising and eco-friendly solution for PPCP remediation, owing to their enhanced catalytic properties and the synergistic effects between the metals. This review critically examines the synthesis, characterization, and application of bimetallic nanoparticles for the degradation of PPCPs in water. Key synthetic approaches, particularly green synthesis methods, are explored, emphasizing their ability to control nanoparticle morphology, size, and composition. We highlight the novel catalytic mechanisms employed by bimetallic nanoparticles, including electron transfer, surface reactions, and adsorption processes, which contribute to efficient PPCP removal. Furthermore, the influence of critical factors such as nanoparticle size, composition, and surface functionalization on catalytic efficiency is analyzed. Key findings include the superior performance of bimetallic nanoparticles over monometallic counterparts, with specific emphasis on their ability to degrade a wide range of PPCPs under mild conditions. However, challenges such as scalability, stability, and environmental impact remain. This review also provides insights into the future directions for bimetallic nanoparticle development, stressing the importance of interdisciplinary research and collaborative efforts to optimize their design for large-scale, sustainable water treatment applications. Overall, this work offers a comprehensive understanding of how bimetallic nanoparticles can be optimized for sustainable water treatment solutions, highlighting their potential to mitigate the adverse effects of PPCPs on both ecosystems and public health.