C        3 symmetric Ru(N^N)3-metalloligand functionalized Zr6-organic frameworks for photocatalytic sulfide and amine oxidation

Si-Min Hou; Ai-Juan Li; Sheng-Li Huang

doi:10.1039/D4CE01002G

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C₃ symmetric Ru(N^N)₃-metalloligand functionalized Zr₆-organic frameworks for photocatalytic sulfide and amine oxidation†

Si-Min Hou,^a Ai-Juan Li*^a and Sheng-Li Huang

*^a

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* Corresponding authors

^a MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China
E-mail: huangsl@bit.edu.cn

Abstract

A photosensitizing network was constructed via the linkage of Zr₆ clusters and an Ru(N^N)₃-metalloligand. It exhibited visible-light-driven photocatalytic activity for sulfide and amine oxidation with high efficiency and product selectivity. Reactive oxygen species (ROS) were studied via quenching experiments, and corresponding photocatalytic mechanisms were explored.

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Article information

DOI: https://doi.org/10.1039/D4CE01002G
Article type: Paper
Submitted: 01 Oct 2024
Accepted: 06 Jan 2025
First published: 07 Jan 2025

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CrystEngComm, 2025,27, 843-849

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C ₃ symmetric Ru(N^N)₃-metalloligand functionalized Zr₆-organic frameworks for photocatalytic sulfide and amine oxidation

S. Hou, A. Li and S. Huang, CrystEngComm, 2025, 27, 843 DOI: 10.1039/D4CE01002G

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