The reaction of in situ-generated lithioferrocene with pnictines EAr3 (E = Sb and Bi, Ar = aryl) is presented as a reliable, robust, and practical approach for synthesising ferrocenyldiarylstibines and bismuthines. In addition to simple derivatives FcEAr2 (Fc = ferrocenyl), the method enables the preparation of functional derivatives, thereby opening access to P,Sb and P,Bi-hybrids.
D. Rezazgui, J. Schulz and P. Štěpnička, Chem. Commun., 2025, 61, 18705 DOI: 10.1039/D5CC05762K
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