RbSb(SO4)(H2PO2)F: a short-wave UV antimony(III) oxysalt with mixed-anions demonstrating enhanced birefringence

Jinwen Tan; Han Luo; Shiyi Wang; Ling Huang; Liling Cao; Xuehua Dong; Guohong Zou

doi:10.1039/D4TC02926G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

RbSb(SO₄)(H₂PO₂)F: a short-wave UV antimony(iii) oxysalt with mixed-anions demonstrating enhanced birefringence†

Jinwen Tan,^a Han Luo,^a Shiyi Wang,^a Ling Huang,

*^a Liling Cao,

^a Xuehua Dong^a and Guohong Zou

*^b

Author affiliations

* Corresponding authors

^a College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610066, P. R. China
E-mail: huangl026@sina.com

^b College of Chemistry, Sichuan University, Chengdu 610065, P. R. China
E-mail: zough@scu.edu.cn

Abstract

A short-wave UV antimony(III) oxysalt, RbSb(SO₄)(H₂PO₂)F, by incorporating three different anions (SO₄²⁻, H₂PO₂⁻, and F⁻) with trivalent antimony cations that possess stereochemically active lone-pair electrons (SCALP), has been successfully synthesized. Synergistic interactions among these units contribute to a substantial birefringence of 0.192 at 546 nm and achieve a short cutoff edge down to 282 nm.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D4TC02926G
Article type: Communication
Submitted: 10 Jul 2024
Accepted: 01 Aug 2024
First published: 02 Aug 2024

Download Citation

J. Mater. Chem. C, 2024,12, 13230-13235

Permissions

Request permissions

RbSb(SO₄)(H₂PO₂)F: a short-wave UV antimony(III) oxysalt with mixed-anions demonstrating enhanced birefringence

J. Tan, H. Luo, S. Wang, L. Huang, L. Cao, X. Dong and G. Zou, J. Mater. Chem. C, 2024, 12, 13230 DOI: 10.1039/D4TC02926G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Journal of Materials Chemistry C