Issue 17, 2024

Dopant clustering and vacancy ordering in neodymium doped ceria

Abstract

Lanthanide doped cerias, show fast oxide ion conduction and have applications as electrolytes in intermediate temperature solid oxide fuel cells. Here, we examine the long- and short-range structures of Ce1−xNdxO2−x/2 (0.05 ≤ x ≤ 0.30, NDC) using reverse Monte Carlo modelling of total neutron scattering data, supported by measurements of electrical behaviour using a.c. impedance spectroscopy. Three distinct features are evident in the local structure of NDC, viz.: clustering of Nd3+ cations, preferred Nd3+-oxide ion vacancy association and oxide ion vacancy clustering with preferential alignment in the 〈100〉 direction. Interestingly, the presence of preferential dopant cation–oxide ion vacancy association is also observed at 600 °C, although diminished compared to the level at room temperature. This suggests a continued contribution of defect association enthalpy to activation energy at elevated temperatures and is reflected in similar compositional variation of high- and low-temperature activation energies.

Graphical abstract: Dopant clustering and vacancy ordering in neodymium doped ceria

Supplementary files

Article information

Article type
Paper
Submitted
11 Dec 2023
Accepted
04 Mar 2024
First published
07 Mar 2024
This article is Open Access
Creative Commons BY license

J. Mater. Chem. A, 2024,12, 10203-10215

Dopant clustering and vacancy ordering in neodymium doped ceria

J. Ming, M. Leszczyńska-Redek, M. Malys, W. Wrobel, J. Jamroz, M. Struzik, S. Hull, F. Krok and I. Abrahams, J. Mater. Chem. A, 2024, 12, 10203 DOI: 10.1039/D3TA07668G

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