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This study presents compelling evidence demonstrating that irradiation of the air–solution interface, whether achieved through the spraying of microdroplets into the air or by bubbling air through a solution, significantly accelerates the rate of photochemical reactions by orders of magnitude compared to identical reaction conditions in bulk solutions. We propose this approach as a novel and versatile method for harnessing solar energy in chemical transformations.

Graphical abstract: The power of microdroplet photochemistry

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