Intricacies of CO2 removal from mixed gases and biogas using polysulfone/ZIF-8 mixed matrix membranes – part 1: experimental

Abstract

In this work, we explore the potential of polysulfone/ZIF-8 mixed matrix membranes (MMMs) for the enrichment of biogas to biomethane. To this end, we present data for these MMMs on permeability and selectivity as function of pressure and feed composition, at different loadings of ZIF-8. Specifically, we study dense polysulfone membranes prepared by solvent evaporation, with a ZIF-8 loading in the range 0.5–5 wt% for separation of CO₂ from artificial mixtures of CO₂ and CH₄, and also biogas from an operating plant. The MMMs with 1 wt% filler loading gave the highest enhancement in permeability and selectivity, of 56.8% and 41% respectively, as compared to pure PSF membranes. At higher loadings, a tendency for the ZIF-8 particles to agglomerate was seen, which may compromise the ability of the filler to improve membrane performance. With mixed gases, increases in CO₂ permeability of about 8 to 34% were observed depending on the gas composition, the enhancement being the higher, the lower the CO₂ content. For biogas, permeability and selectivity of the 1% ZIF-8 loaded MMMs were found to be 14.6% and 39.64% lesser respectively than the pure gas values. The study thus throws light on the differences in membrane performance with mixtures as compared to ideal values obtained with pure gases and hence underlines the importance of lab-scale testing of the membranes with actual gas mixtures in the intended applications.