A review on carbon quantum dot/semiconductor-based nanocomposites as hydrogen production photocatalysts

Abstract

Carbon quantum dots (CQDs) are discrete, quasi-spherical carbon nanoparticles with sizes below 10 nm. The properties of CQDs can be further enhanced by doping with elements such as nitrogen, phosphorous, sulphur, and boron or co-doping with heteroatoms such as nitrogen–phosphorous, nitrogen–sulphur, and nitrogen–boron. These excellent properties of CQDs can be utilized to enhance the photocatalytic performance of semiconductors. Therefore, in this review, we summarize different types of bare CQD-scaffolded semiconductors, both doped and co-doped, used for photocatalytic hydrogen production. Moreover, the detailed photocatalytic mechanism of CQD/semiconductor-based hydrogen production is reviewed. Recent progress in the design and development of CQD-based photocatalysts, along with the challenges involved, is comprehensively reviewed.