Aliphatic hyperbranched polyphosphate: a novel multicolor RTP material with AIE character

Abstract

Long-lived photoluminescent probes are emerging as significant luminogens for biological imaging. However, currently, most long-lived luminescent materials contain expensive rare elements or cytotoxic bulky aromatic or conjugated units. Herein, a novel hyperbranched polyphosphate (HBPPE) was synthesized using triethyl phosphate (TEP) and ethylene glycol (EG) through a transesterification polycondensation reaction. The obtained HBPPE P1 can emit bright blue photoluminescence under UV light and show significant AIE character. Interestingly, the average photoluminescence lifetime of P1 is 12.82 μs. This suggests the first phosphorescent material without rare elements or aromatic structures attributed to the covalent-crystal-like structure. Besides, P1 shows an obvious red-shift along with the excitation wavelength, which emits blue, cyan, green, yellow and red photoluminescence, covering nearly all the visible light region. This study not only enriches the species of nonconventional multicolor AIE luminogens but also provides a concise method for the synthesis of HBPPE and demonstrates the possibility for phosphorescent materials without rare elements or bulky aromatic units.