Synthesis of graphitic carbon nitride-based nanocomposites and their mechanical properties in epoxy compositions

Abstract

Thermoset epoxy resins are widely used in research and commercial applications. Zeolite imidazole framework-8 (ZIF-8), graphitic carbon nitride (GCN, g-C₃N₄), and S-doped graphitic carbon nitride (SCN, S-g-C₃N₄) composites were synthesized as accelerators and their effects on the physical properties of epoxies were examined. An ultrasound-assisted method was used to prepare ZIF-8/GCN and ZIF-8/SCN nanocomposites while g-C₃N₄ and S-g-C₃N₄ were prepared from the calcination of melamine and thiourea, respectively. The surface morphology, and particle size were characterized by scanning electron microscopy, and X-ray diffraction. The properties of synthesized nanocomposites were measured using Fourier-transform infrared spectroscopy. After the accelerator was added to the epoxy composites, their activation energies were calculated using differential scanning calorimetry. The tensile strength and flexural strength were measured using a universal testing machine and impact strength was measured by using an Izod impact strength tester. The impact strength of ZIF-8/SCN nanocomposites was enhanced by 45.2%. The storage stability of the epoxy compositions with different catalysts was evaluated by measuring the variation of viscosity with time at a constant temperature.