Issue 20, 2024, Issue in Progress

Scanning electrochemical microscopy for the differentiation of radical-induced degradation mechanisms in polymer electrolyte membranes

Abstract

In this work, a spatially resolved analytical method based on scanning electrochemical microscopy (SECM) to distinguish different degradation phenomena in polymer electrolyte membranes was developed. SECM was combined with a Franz diffusion cell to distinguish between radical-induced aging of a sulfonated tetrafluoroethylene based fluoropolymer-copolymer due to deactivation of the sulfonic acid groups followed by a decreased proton conductivity, and the radical-induced formation of cracks and holes in the polymer. The experiments were performed with ferrocyanide as redox mediator to detect holes and cracks, and protons (sulfuric acid) to determine the through-plane proton conductivity, respectively. A pristine Nafion™ membrane, a pristine Nafion™ membrane with an artificial pinhole and a Nafion™ membrane aged with Fenton's reagent were investigated to prove the measurement principle. It could be shown that holes and cracks can be reliably detected with this approach and discriminated from a change in proton conductivity. The presence of holes in the investigated aged membranes was confirmed by scanning electron microscopy, whereas the loss of sulfonate groups could be supported by infrared spectroscopy measurements.

Graphical abstract: Scanning electrochemical microscopy for the differentiation of radical-induced degradation mechanisms in polymer electrolyte membranes

Article information

Article type
Paper
Submitted
22 Mar 2024
Accepted
16 Apr 2024
First published
26 Apr 2024
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2024,14, 13748-13757

Scanning electrochemical microscopy for the differentiation of radical-induced degradation mechanisms in polymer electrolyte membranes

S. Thiel and M. Eichelbaum, RSC Adv., 2024, 14, 13748 DOI: 10.1039/D4RA02203C

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