Issue 5, 2024, Issue in Progress

Acid–base equilibrium in non-aqueous medium: colorimetric visualization, estimation of acidity constants and construction of molecular logic gates

Abstract

A reversible acid–base probe, (N1E, N4E)-N1, N4-bis((Z)-3-(4-(dimethylamino)phenyl)allylidene)benzene-1,4-diamine (MM1), is introduced for the colorimetric visualization of acid–base equilibria in non-aqueous media. MM1 displays reversible acidochromic behavior, showing exciting colorimetric change varying from weak to strong acid. Also, we have fabricated a colorimetric paper strip-based test kit to visualize acid–base equilibria. A dipstick experiment has been demonstrated to visualize the acid–base equilibria in the gaseous state. This acid–base probe has also been employed to estimate the pKa values of several acidic compounds in a non-aqueous medium using overlapping indicator methods. Based on reversible acidochromic UV-visible absorption spectral and colorimetric behavior, we have constructed a reconfigurable dual input and dual output combinational logic circuit and set-reset memorized device employing acid and base as chemically encoded inputs and corresponding optical outputs. The current report evokes a new protocol for developing various reversible acidochromic probes and its implication for constructing opto-chemical molecular logic gates and estimating the acid dissociation constants of various acidic compounds in non-aqueous media.

Graphical abstract: Acid–base equilibrium in non-aqueous medium: colorimetric visualization, estimation of acidity constants and construction of molecular logic gates

Supplementary files

Transparent peer review

To support increased transparency, we offer authors the option to publish the peer review history alongside their article.

View this article’s peer review history

Article information

Article type
Paper
Submitted
13 Jul 2023
Accepted
09 Jan 2024
First published
22 Jan 2024
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2024,14, 3480-3488

Acid–base equilibrium in non-aqueous medium: colorimetric visualization, estimation of acidity constants and construction of molecular logic gates

M. Mahato, A. Maiti, S. Ahamed, M. Rajbanshi, S. Lama and S. K. Das, RSC Adv., 2024, 14, 3480 DOI: 10.1039/D3RA04696F

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements