Issue 16, 2024
From the journal:

Organic Chemistry Frontiers

Copper-catalyzed pentafluoroethylation of aryl/alkenyl iodides with pentafluoroethylsilane†

Yihan Tang ORCID logo a  and  Gavin Chit Tsui ORCID logo *a  

* Corresponding authors

a Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, China
E-mail: gctsui@cuhk.edu.hk

Abstract

A copper-catalyzed pentafluoroethylation of aryl/alkenyl iodides is described using Et3SiCF2CF3 as a direct CF2CF3 source. An intriguing selective photocatalytic hydrodefluorination of pentafluoroethylarenes is also discovered.

Graphical abstract: Copper-catalyzed pentafluoroethylation of aryl/alkenyl iodides with pentafluoroethylsilane

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Article information

DOI
https://doi.org/10.1039/D4QO00433G
Article type
Research Article
Submitted
07 Mar 2024
Accepted
03 Jul 2024
First published
04 Jul 2024

Org. Chem. Front., 2024,11, 4366-4370

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Copper-catalyzed pentafluoroethylation of aryl/alkenyl iodides with pentafluoroethylsilane

Y. Tang and G. C. Tsui, Org. Chem. Front., 2024, 11, 4366 DOI: 10.1039/D4QO00433G

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