Here, we report on a microwave-assisted accelerated meta-C–H olefination of aniline derivatives using a simple aliphatic end-on nitrile assembly. Notably, the protocol shows broad substrate compatibility with remarkable regio-selectivity. It also showcases the removal of amide-based linkage and the template to furnish the meta-olefinated aniline derivative.
D. Srinivas and G. Satyanarayana, Org. Chem. Front., 2024, 11, 1473 DOI: 10.1039/D3QO01943H
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