Aggregation induced emission and volatile acid vapour sensing in acridine appended poly (aryl ether) based low molecular weight organogelator

Abstract

Considerable research attention has been devoted to the development of portable and rapid fluorescence sensors that can selectively detect volatile acids, due to the harmful effects of acid vapour on the environment and human health. Although various types of fluorophores have been reported for sensing volatile acid vapours, regulation of the sensory response using aggregation induced emissive (AIE) based gelators has rarely been reported. In this study, we present the design and synthesis of a novel organogelator that is capable of sensing volatile acids through AIE. An acridine-attached poly(aryl ether) dendron molecular system is synthesized through an aldimine coupling reaction, which self-assembles and forms a gel, exhibiting AIE behavior. The synthesized molecule and prepared gel were characterized using NMR, MASS, XRD, HRSEM and rheology techniques. The AIE property of APD was investigated using steady-state absorption and emission spectroscopic techniques. The sensory response of the APD gelator was tested with various analytes, and the results indicated that APD shows rapid response, particularly to acid vapours, where the detection limits (DL) of trifluoroacetic acid (TFA), hydrochloric acid (HCl) and nitric acid (HNO₃) vapor were as low as 0.22, 0.9 and 0.30 ppm, respectively. An APD solid film in filter paper shows a visual color change from yellow to red in an aqueous acidic medium, and the effect is reversed in an alkaline medium. These findings suggest that an APD gelator could potentially be utilized to generate a portable acid vapor sensor kit due to its low detection limit and rapid response time, and it could be also be used as a substitute for existing acid indicators.