Synthesis of Cs-symmetrical C60 tetra-adducts via reactions of C60Cl6 with CH-acids and enol silyl ester

Olga A. Kraevaya; Alexander S. Peregudov; Alexander F. Shestakov; Pavel A. Troshin

doi:10.1039/D3OB01868G

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Synthesis of C_s-symmetrical C₆₀ tetra-adducts via reactions of C₆₀Cl₆ with CH-acids and enol silyl ester†

Olga A. Kraevaya,

*^a Alexander S. Peregudov,

^b Alexander F. Shestakov

*^ac and Pavel A. Troshin

^ad

Author affiliations

* Corresponding authors

^a Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of RAS, Semenov Prospect 1, Chernogolovka, Russia
E-mail: okraevaya@inbox.ru, a_shestakov@list.ru

^b A.N. Nesmeyanov Institute of Organoelement compounds of RAS, Vavylova St. 28, B-334, Moscow, Russia

^c Department of Fundamental Physics & Chemical Engineering, M.V. Lomonosov Moscow State University, Leninskie Gory 1/51, Moscow, Russia

^d Zhengzhou Research Institute, Harbin Institute of Technology, Longyuan East 7th 26, Jinshui District, Zhengzhou, Henan Province, China

Abstract

Here we report the synthesis of novel fullerene derivatives with attached aliphatic residues based on the previously unknown reactions of chlorofullerene C₆₀Cl₆ with CH-acids and silyl enol ether.

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Article information

DOI: https://doi.org/10.1039/D3OB01868G
Article type: Paper
Submitted: 16 Nov 2023
Accepted: 05 Dec 2023
First published: 05 Dec 2023

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Org. Biomol. Chem., 2024,22, 374-379

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Synthesis of C_s-symmetrical C₆₀ tetra-adducts via reactions of C₆₀Cl₆ with CH-acids and enol silyl ester

O. A. Kraevaya, A. S. Peregudov, A. F. Shestakov and P. A. Troshin, Org. Biomol. Chem., 2024, 22, 374 DOI: 10.1039/D3OB01868G

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Organic & Biomolecular Chemistry