Issue 29, 2024

Passive fractionating mechanism for oil spill using shear-wettability modulation

Abstract

Oil spillage and organic solvent leakage have been a frequent occurrence in recent years, which pose a significant threat not only to the aquatic ecosystems but also result in substantial economic burdens. This has necessitated the search for materials capable of separating oil from water at enhanced efficiency with superior mechanical and thermal properties. In this study, we conduct a set of systematic molecular dynamics simulations to investigate the potential of two-dimensional graphene-like channels under extreme confinement to achieve efficient oil–water separation. Effective modulation of the wetting characteristics of graphene-like surfaces juxtaposed with unconventional flow behavior at the nanoscale unveils differential interaction of water and oil molecules towards the wall, thereby resulting in distinct separation zones for varying compositions of the oil–water mixture. Such separation zones have been observed to be highly correlated with mixture temperature, which provides effective separation pathways across diverse environmental conditions. Our study offers a paradigm shift in oil–water separation strategies, which not only provides deeper insights into the equilibrium and dynamic behavior of a two-phase mixture but also holds immense implications for the development of smart, wettability-based oil separation devices.

Graphical abstract: Passive fractionating mechanism for oil spill using shear-wettability modulation

Supplementary files

Article information

Article type
Paper
Submitted
20 Mar 2024
Accepted
04 Jun 2024
First published
05 Jun 2024

Nanoscale, 2024,16, 13885-13894

Passive fractionating mechanism for oil spill using shear-wettability modulation

V. Arya, A. Chaudhuri and C. Bakli, Nanoscale, 2024, 16, 13885 DOI: 10.1039/D4NR01235F

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