Issue 28, 2024

Clustering triggered emissive liquid crystalline template for dual mode upconverted and downconverted circularly polarized luminescence

Abstract

Liquid crystalline materials have attracted significant attention in chiroptical research due to their ability to form long range ordered helical superstructures. Research focus has been on exploiting the unique properties of liquid crystalline materials to demonstrate highly dissymmetric circularly polarised luminescent (CPL) systems. In this study, we present a thermally driven, facile approach to fabricate CPL-active materials utilizing cholesteryl benzoate as the active substrate. Cholesteryl benzoate, a well-known thermotropic liquid crystal, has been found to manifest intriguing optical characteristics upon subjecting to repeated heating–cooling cycles. Despite the absence of conventional fluorescent moieties, the material exhibited luminescence through aggregation induced clustering triggered emission mechanism. Systematic investigations revealed excitation-dependent CPL for solid cholesteryl benzoate films when subjected to multiple thermal cycles. The excited state chiroptical investigation performed after multiple thermal cycles showed a luminescence anisotropy (glum) of 8 × 10−2, which is a high value for simple organic molecules. Moreover, upon co-assembly with lanthanide-based upconversion nanophosphors (UCNPs), the hybrid system demonstrated upconverted circularly polarised luminescence (UC-CPL). Benefiting from the ability to endow upconversion nanoparticles of various sizes, fabrication of UCNP-ChB hybrid nanocomposites exhibiting multicoloured upconversion CPL was demonstrated. These findings highlight the potential of liquid crystalline materials for diverse applications, including 3D optical displays and anticounterfeiting technologies.

Graphical abstract: Clustering triggered emissive liquid crystalline template for dual mode upconverted and downconverted circularly polarized luminescence

Supplementary files

Article information

Article type
Paper
Submitted
29 Feb 2024
Accepted
25 Jun 2024
First published
27 Jun 2024
This article is Open Access
Creative Commons BY license

Nanoscale, 2024,16, 13571-13579

Clustering triggered emissive liquid crystalline template for dual mode upconverted and downconverted circularly polarized luminescence

S. T. Nalavadath, S. Maniappan, A. Mandal and J. Kumar, Nanoscale, 2024, 16, 13571 DOI: 10.1039/D4NR00865K

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