Issue 29, 2024

The new dual anion solvent-free nickel complex based on the pyridine-4-carbohydrazide ligand

Abstract

Based on the ideas of coordination and design chemistry, we propose a new strategy to balance the energy and sensitivity conflict by synthesizing dual anion structures in the realm of energetic complex compounds. Therefore, a novel solvent-free complex, [Ni(4-PDCA)2(NO3)2](ClO4)2 (ECCs-1), which has a six-coordinated octahedral structure and contains dual anions, was synthesized. The structure was identified by IR, EA and single-crystal XRD. To the best of our knowledge, it is the first reported dual anion structure that exhibits excellent insensitivity with acceptable thermal stability and detonation performance.

Graphical abstract: The new dual anion solvent-free nickel complex based on the pyridine-4-carbohydrazide ligand

Supplementary files

Article information

Article type
Communication
Submitted
04 May 2024
Accepted
23 Jun 2024
First published
24 Jun 2024

New J. Chem., 2024,48, 12873-12876

The new dual anion solvent-free nickel complex based on the pyridine-4-carbohydrazide ligand

B. Kuang, B. Zhao, Z. Lu, T. Wang, Z. Xie, M. Sun, Q. Yu and J. Zhang, New J. Chem., 2024, 48, 12873 DOI: 10.1039/D4NJ02087A

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