Issue 20, 2024
From the journal:

New Journal of Chemistry

Photocatalyst-free hydrothiolation of gem-difluoroalkenes with thiols†

Lin Zuo,a   Zhiyang Zhang,a   Xiao-Ya Yuan,ab   Kai Sun ORCID logo *a  and  Bing Yu ORCID logo *a  

* Corresponding authors

a College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
E-mail: sunkaichem@zzu.edu.cn, bingyu@zzu.edu.cn

b National Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass, Nanjing Forestry University, Nanjing 210037, China

Abstract

A photocatalyst-free hydrothiolation reaction of aromatic gem-difluoroalkenes was developed under the irradiation of blue light in dimethyl carbonate as a green solvent, leading to α,α-difluoroalkylthioethers in good yields.

Graphical abstract: Photocatalyst-free hydrothiolation of gem-difluoroalkenes with thiols

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Article information

DOI
https://doi.org/10.1039/D4NJ01571A
Article type
Communication
Submitted
04 Apr 2024
Accepted
28 Apr 2024
First published
29 Apr 2024

New J. Chem., 2024,48, 9000-9003

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Photocatalyst-free hydrothiolation of gem-difluoroalkenes with thiols

L. Zuo, Z. Zhang, X. Yuan, K. Sun and B. Yu, New J. Chem., 2024, 48, 9000 DOI: 10.1039/D4NJ01571A

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