Issue 11, 2024

Internal Coulombic assistance in intermolecular frustrated Lewis pair activation of dihydrogen

Abstract

1,3-Zwitterions consisting of a phosphonium cation linked to a silicate centre through a one-atom bridge, X3P–E–SiY4 (3), are computationally studied. Their phosphonium acidic group together with a Lewis base constitute a frustrated Lewis pair (FLP) in the activation of H2, with the silicate side-arm providing Coulombic stabilization to the positive charge at the Lewis base.

Graphical abstract: Internal Coulombic assistance in intermolecular frustrated Lewis pair activation of dihydrogen

Supplementary files

Article information

Article type
Communication
Submitted
31 Jan 2024
Accepted
14 Feb 2024
First published
15 Feb 2024
This article is Open Access
Creative Commons BY-NC license

New J. Chem., 2024,48, 4675-4679

Internal Coulombic assistance in intermolecular frustrated Lewis pair activation of dihydrogen

A. Rey Planells, A. Espinosa Ferao, R. Streubel and A. Frontera, New J. Chem., 2024, 48, 4675 DOI: 10.1039/D4NJ00523F

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