Hierarchical chirality transfer of perylene diimide-tethered pillar[5]arenes for configuration and type differentiation of amino acid derivatives

Ting Zhao; Jigao Yi; Chunhong Liu; Lizhi Fang; Long Chen; Yanlin Shen; Xiaotong Liang; Kun Li; Wanhua Wu; Cheng Yang

doi:10.1039/D3NJ05420A

Hierarchical chirality transfer of perylene diimide-tethered pillar[5]arenes for configuration and type differentiation of amino acid derivatives†

Ting Zhao,^a Jigao Yi,^a Chunhong Liu,^a Lizhi Fang,^a Long Chen,^a Yanlin Shen,^a Xiaotong Liang,^a Kun Li,

^a Wanhua Wu

*^a and Cheng Yang

*^a

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* Corresponding authors

^a Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry Institution, Sichuan University, Chengdu 610064, China
E-mail: yangchengyc@scu.edu.cn

Abstract

Perylene diimide-tethered pillar[5]arene derivatives showed significantly varied circular dichroism (CD) spectral responses towards different amino acid derivatives in both the dispersed and aggregated forms. The wide variety of patterns and intensity combinations of CD signals at different wavelengths allowed for the differentiation of not only the configuration but also types of amino acid derivatives with only one chiroptical sensor.

New Journal of Chemistry

Hierarchical chirality transfer of perylene diimide-tethered pillar[5]arenes for configuration and type differentiation of amino acid derivatives†

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Hierarchical chirality transfer of perylene diimide-tethered pillar[5]arenes for configuration and type differentiation of amino acid derivatives

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