Issue 2, 2024
From the journal:

New Journal of Chemistry

A redox switchable ferrocene decorated n-heterocyclic carbene (NHC) palladium catalyst for cross coupling of arylboronic acid and acetic anhydride in phosphine, base and additive free conditions†‡

Debashree Bora, ORCID logo ab   Abdul Aziz Ali ORCID logo ac  and  Biswajit Saha ORCID logo *ab  

* Corresponding authors

a Bimetallic Catalysis Lab, Advanced Materials Group, Materials Sciences and Technology Division, CSIR-North East Institute of Science and Technology, Jorhat, Assam 785006, India
E-mail: bsaha@neist.res.in, bischem@gmail.com

b Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

c Presently at Dhemaji Engineering College, Dhemaji, Assam 787057, India

Abstract

A phosphine, base and additive free cross-coupling of arylboronic acid is reported via C–O bond cleavage of acetic anhydride using a switchable ferrocene functionalized n-heterocyclic carbene (NHC) palladium complex. The novel redox active catalytic system afforded the corresponding arylketones with good to excellent yields.

Graphical abstract: A redox switchable ferrocene decorated n-heterocyclic carbene (NHC) palladium catalyst for cross coupling of arylboronic acid and acetic anhydride in phosphine, base and additive free conditions

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Article information

DOI
https://doi.org/10.1039/D3NJ04997C
Article type
Paper
Submitted
30 Oct 2023
Accepted
20 Nov 2023
First published
20 Nov 2023

New J. Chem., 2024,48, 615-620

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A redox switchable ferrocene decorated n-heterocyclic carbene (NHC) palladium catalyst for cross coupling of arylboronic acid and acetic anhydride in phosphine, base and additive free conditions

D. Bora, A. A. Ali and B. Saha, New J. Chem., 2024, 48, 615 DOI: 10.1039/D3NJ04997C

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