Issue 12, 2024

Helical interfacial modulation for perovskite photovoltaics

Abstract

Hybrid metal halide perovskites have demonstrated remarkable performances in modern photovoltaics, although their stabilities remain limited. We assess the capacity to advance their properties by relying on interfacial modulators featuring helical chirality based on P,M-(1-methylene-3-methyl-imidazolium)[6]helicene iodides. We investigate their characteristics, demonstrating comparable charge injection for enantiomers and the racemic mixture. Overall, they maintain the resulting photovoltaic performance while improving operational stability, challenging the role of helical chirality in the interfacial modulation of perovskite solar cells.

Graphical abstract: Helical interfacial modulation for perovskite photovoltaics

Supplementary files

Article information

Article type
Communication
Submitted
09 Jan 2024
Accepted
06 May 2024
First published
30 May 2024
This article is Open Access
Creative Commons BY-NC license

Nanoscale Adv., 2024,6, 3029-3033

Helical interfacial modulation for perovskite photovoltaics

G. AlSabeh, M. Almalki, S. Kasemthaveechok, M. A. Ruiz-Preciado, H. Zhang, N. Vanthuyne, P. Zimmermann, D. M. Dekker, F. T. Eickemeyer, A. Hinderhofer, F. Schreiber, S. M. Zakeeruddin, B. Ehrler, J. Crassous, J. V. Milić and M. Grätzel, Nanoscale Adv., 2024, 6, 3029 DOI: 10.1039/D4NA00027G

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