Issue 4, 2024

Kirkendall effect induced ultrafine VOOH nanoparticles and their transformation into VO2(M) for energy-efficient smart windows

Abstract

Vanadium dioxide (VO2) has received widespread attention for application in energy-efficient smart windows because of its distinct thermochromic property in the near-infrared region during the reversible metal–insulator phase transition. In this study, lepidocrocite VOOH ultrafine nanoparticles (NPs) with a diameter less than 30 nm were prepared by a mild and efficient hydrothermal method, and the Kirkendall effect played a vital role in the growth of the VOOH NPs. It was found that VOOH could be transformed into VO2via a subsequent annealing treatment during which the size and morphology of VOOH are well preserved even though the annealing temperature is up to 500 °C. The ultrafine VO2 NPs are crucial for achieving excellent nanothermochromic performance with a luminous transmittance (Tlum) up to 56.45% and solar modulation ability (ΔTsol) up to 14.95%. The environmental durability is well improved by coating VO2 NPs with an SiO2 shell as confirmed via progressive oxidation and acid corrosion experiments. Meanwhile, the Tlum of the VO2@SiO2 film is further increased from 56.45% to 62.29% while the ΔTsol remained unchanged. This integrated thermochromic performance presents great potential for the development of VO2-based smart windows.

Graphical abstract: Kirkendall effect induced ultrafine VOOH nanoparticles and their transformation into VO2(M) for energy-efficient smart windows

  • This article is part of the themed collection: #MyFirstMH

Supplementary files

Article information

Article type
Communication
Submitted
01 Sep 2023
Accepted
30 Nov 2023
First published
04 Dec 2023
This article is Open Access
Creative Commons BY-NC license

Mater. Horiz., 2024,11, 1098-1107

Kirkendall effect induced ultrafine VOOH nanoparticles and their transformation into VO2(M) for energy-efficient smart windows

L. Wu, A. Teng, M. Li, L. Li, Z. Huang, X. Li, J. Yu, S. Xu, F. Zou, A. Zou, J. Zhang, T. Jiang, Y. Xin, X. Hu and G. Li, Mater. Horiz., 2024, 11, 1098 DOI: 10.1039/D3MH01393F

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