Issue 4, 2024

Valorization of plastic waste via chemical activation and carbonization into activated carbon for functional material applications

Abstract

Addressing the complex issue of plastic waste disposal requires a nuanced approach, as no single solution proves universally effective. This review advocates for a comprehensive strategy, combining mechanical recycling and chemical methods to manage plastic waste while emphasizing the transformative potential of carbonization and activation processes specifically. With a focus on chemical activation, this review explores the synthesis of high surface area activated carbon (AC) from diverse plastic sources including polyesters (e.g., polyethylene terephthalate), polyolefins (e.g., polyethylene, polypropylene), and non-recyclable thermoset resins (e.g., epoxy, phenolics). The resulting AC products exhibit notable potential, with high surface areas exceeding 2000 m2 g−1 in some cases. Furthermore, the adsorptive behavior of the plastic derived ACs are discussed with respect to common pollutants such as dyes and CO2 in addition to emerging pollutants, such as micro/nano-plastics. Overall, this work highlights carbonization and chemical activation as important upcycling methods for plastic wastes that may otherwise end up in landfills or spills into the environment. Given the urgency of plastic waste disposal, it is recommended that the feasibility and scalability of plastic-derived AC production is explored in future work for the potential replacement of conventional AC feedstocks derived from coal or biomass.

Graphical abstract: Valorization of plastic waste via chemical activation and carbonization into activated carbon for functional material applications

Article information

Article type
Review Article
Submitted
18 Jan 2024
Accepted
09 Mar 2024
First published
19 Mar 2024
This article is Open Access
Creative Commons BY license

RSC Appl. Polym., 2024,2, 557-582

Valorization of plastic waste via chemical activation and carbonization into activated carbon for functional material applications

R. Blanchard and T. H. Mekonnen, RSC Appl. Polym., 2024, 2, 557 DOI: 10.1039/D4LP00016A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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