Issue 7, 2024

Zirconium analysis in microscopic spent nuclear fuel samples by resonance ionization mass spectrometry

Abstract

We developed a Zr two-photon resonance ionization scheme with a high useful yield of 6.3(5)%. This scheme utilizes the known intermediate energy level at 26443.88 cm−1 and a newly characterized Rydberg level at 53490.79(26) cm−1. Both the first (378.16 nm) and second (369.727 nm) transition wavelengths are accessible by frequency-doubled titanium:Sapphire lasers. We utilize the new scheme to analyze the isotopics of Zr, a fission product, in micrometer-sized spent nuclear fuel samples to understand their irradiation history. This includes the dependence on burnup and radial location within a fuel pellet. Resonance ionization mass spectrometry was used to obtain almost isobar-free Zr isotopic ratios from seven samples. The measured isotopic ratios from the spent nuclear fuel show a strong dependence on radial position within the fuel pellet while the effect of average pellet burnup was much less pronounced. All Zr isotopic ratios systematically change from the pellet center to the pellet edge, where isotopic values are close to those expected from 235U fission and 239Pu fission, respectively. Using Zr isotopics, we demonstrate a potential method to distinguish between samples derived from the edge or center of a fuel element of unknown pedigree, which strongly impacts the interpretation of a sample's irradiation history as the neutron fields are different between these locations.

Graphical abstract: Zirconium analysis in microscopic spent nuclear fuel samples by resonance ionization mass spectrometry

Supplementary files

Article information

Article type
Paper
Submitted
22 Feb 2024
Accepted
15 May 2024
First published
16 May 2024
This article is Open Access
Creative Commons BY-NC license

J. Anal. At. Spectrom., 2024,39, 1803-1812

Zirconium analysis in microscopic spent nuclear fuel samples by resonance ionization mass spectrometry

M. Raiwa, M. Savina, D. Z. Shulaker, A. Roberts and B. Isselhardt, J. Anal. At. Spectrom., 2024, 39, 1803 DOI: 10.1039/D4JA00065J

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