Issue 15, 2024

Continuous-flow directed C–H amidation reactions using immobilized Cp*Rh(iii) catalysts

Abstract

We report a green, continuous-flow C–H amidation methodology using heterogeneous Cp*Rh(III) catalysts. These catalysts enable halide- and salt-free reactions with excellent activity and durability across diverse substrates, demonstrated by a 200-hour, multi-gram scale reaction exceeding 290 TON (turnover number).

Graphical abstract: Continuous-flow directed C–H amidation reactions using immobilized Cp*Rh(iii) catalysts

Supplementary files

Article information

Article type
Communication
Submitted
09 Apr 2024
Accepted
25 Jun 2024
First published
27 Jun 2024

Green Chem., 2024,26, 8680-8684

Continuous-flow directed C–H amidation reactions using immobilized Cp*Rh(III) catalysts

Y. Saito, T. Konno and S. Kobayashi, Green Chem., 2024, 26, 8680 DOI: 10.1039/D4GC01747A

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