Volume 2, 2024

Recent advances in tunable metal–support interactions for enhancing the photocatalytic nitrogen reduction reaction

Abstract

Ammonia (NH3), as an important foundational chemical and green hydrogen energy carrier, plays an indispensable role in the development of human society. However, it is evident that the traditional process for NH3 synthesis is no longer in line with the times due to its drawbacks, such as high energy consumption and high carbon emission. In recent years, the photocatalytic nitrogen reduction reaction (PNRR), which reduces N2 to NH3 under mild conditions using inexhaustible solar energy, has been considered as a promising alternative. Nevertheless, the catalytic efficiency of the PNRR is low and far from realizing practical applications owing to the weak N2 adsorption, hard dissociation of inert N[triple bond, length as m-dash]N, and competing reactions of hydrogen precipitation. Metal–support interactions (MSIs) provide an efficient way to adjust the performance of both the active metal and support in the photocatalytic process through geometric, electronic and bifunctional effects. The design of heterogeneous photocatalysts with tunable MSIs has been proved to be a feasible way to enhance their catalytic performance for the PNRR. In this review, we summarize the recent developments in MSI photocatalysts involved in nitrogen fixation. Firstly, the mechanism of MSIs and their characterization as well as the synthesis strategies for photocatalysts with MSIs are briefly outlined. Subsequently, the electronic and bifunctional effects of MSI photocatalysts and the corresponding PNRR mechanism are focused on, from the aspects of supports such as metal oxides, bismuth oxyhalides, metal sulfides, metal–organic frameworks (MOFs) and carbon nitrides. Finally, the future developments in this area such as creating state-of-the-art materials with MSIs and synthesis strategies and developing advanced techniques to investigate reaction mechanisms for N2 fixation are discussed. It is expected that this review can provide some guidance for understanding and rationally designing MSI photocatalysts, especially for boosting the PNRR.

Graphical abstract: Recent advances in tunable metal–support interactions for enhancing the photocatalytic nitrogen reduction reaction

Article information

Article type
Review Article
Submitted
04 Aug 2023
Accepted
06 Sep 2023
First published
15 Sep 2023
This article is Open Access
Creative Commons BY-NC license

EES. Catal., 2024,2, 180-201

Recent advances in tunable metal–support interactions for enhancing the photocatalytic nitrogen reduction reaction

B. Wang, G. Chen, B. Hu, L. Chen, X. Wang, S. Tian, X. Hu, Y. Li, C. Peng and S. Yin, EES. Catal., 2024, 2, 180 DOI: 10.1039/D3EY00191A

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements