Issue 34, 2024

Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

Abstract

This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation.

Graphical abstract: Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

Supplementary files

Article information

Article type
Paper
Submitted
24 May 2024
Accepted
24 Jul 2024
First published
13 Aug 2024
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2024,53, 14212-14218

Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

P. Jurt, J. J. Gamboa-Carballo, C. Schweinzer, D. Himmelbauer, D. Thöny, T. L. Gianetti, M. Trincado and H. Grützmacher, Dalton Trans., 2024, 53, 14212 DOI: 10.1039/D4DT01520G

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