Carbonic anhydrase-mimicking metal–organic frameworks built from amino acid and cadmium ions

Taofeek Ogungbade; Charles Uland; Longji Li; Luhan Wang; Kareena Pansuria; Carolina Relva; Gregory Barn; Simrat Jeet Kaur; Paulin Norris; Bangbo Yan

doi:10.1039/D4DT01456A

Carbonic anhydrase-mimicking metal–organic frameworks built from amino acid and cadmium ions†

Taofeek Ogungbade,^a Charles Uland,^a Longji Li,^a Luhan Wang,^a Kareena Pansuria,^a Carolina Relva,^a Gregory Barn,^a Simrat Jeet Kaur,^a Paulin Norris^b and Bangbo Yan

*^ab

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^a Department of Chemistry, Western Kentucky University, 1906 College Heights Blvd., Bowling Green, KY 42101, USA
E-mail: bangbo.yan@wku.edu

^b Advanced Materials Institute, Western Kentucky University, 2413 Nashville Rd., Bowling Green, KY 42101, USA

Abstract

Built from L-histidine amino acid ligand and cadmium ions, two new 3D chiral metal–organic frameworks, [α-Cd(HIS)] (1) and [β-Cd(HIS)] (2), which contain metal-histidine bonds mimicking the structure features of carbonic anhydrase, demonstrate interesting properties of catalyzing the hydrolysis of p-nitrophenylacetate (p-NPA) to para-nitrophenol (p-NP).

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Carbonic anhydrase-mimicking metal–organic frameworks built from amino acid and cadmium ions†

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Carbonic anhydrase-mimicking metal–organic frameworks built from amino acid and cadmium ions

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