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We report superionic conduction in a Mg2+-containing covalent organic framework (COF) at intermediate temperature in the absence of guest vapors. A COF containing Mg2+ carriers and polyethylene oxide (PEO) chains in its channels (TPB-PEO-9-COF-Mg) was synthesized. TPB-PEO-9-COF-Mg showed superionic conductivity above 10−4 S cm−1 under dry N2 at 160 °C.
A. Mohri, Y. Oami and M. Sadakiyo, Dalton Trans., 2024, 53, 13326 DOI: 10.1039/D4DT01424C
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