{Mo4}-directed structural evolution of highly reduced molybdenum red clusters for efficient proton conduction

Bingbing Li; Yuxin Lan; Heyang Su; Jiaxin Xu; Qixin Zhao; Yubin Ma; Qi Zheng; Weimin Xuan

doi:10.1039/D4DT00187G

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{Mo₄}-directed structural evolution of highly reduced molybdenum red clusters for efficient proton conduction†

Bingbing Li,^a Yuxin Lan,^a Heyang Su,^a Jiaxin Xu,^a Qixin Zhao,^a Yubin Ma,^a Qi Zheng

*^b and Weimin Xuan

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, P R China
E-mail: weiminxuan@dhu.edu.cn

^b State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering, Donghua University, Shanghai 201620, P R China
E-mail: qi.zheng@dhu.edu.cn

Abstract

A series of highly reduced Mo red clusters {Mo₂₈} (1), {Mo₃₀} (2), and {Mo₄₀} (3) are synthesized from the rational assembly of planar {Mo^V₄} building blocks and employed for proton conduction. 3 exhibits the best conductivity of 7.56 × 10⁻³ S cm⁻¹ under optimal conditions due to the most efficient hydrogen-bonding network.

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Article information

DOI: https://doi.org/10.1039/D4DT00187G
Article type: Communication
Submitted: 21 Jan 2024
Accepted: 13 Mar 2024
First published: 15 Mar 2024

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Dalton Trans., 2024,53, 6184-6189

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{Mo₄}-directed structural evolution of highly reduced molybdenum red clusters for efficient proton conduction

B. Li, Y. Lan, H. Su, J. Xu, Q. Zhao, Y. Ma, Q. Zheng and W. Xuan, Dalton Trans., 2024, 53, 6184 DOI: 10.1039/D4DT00187G

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