Issue 16, 2024
From the journal:

Dalton Transactions

Field induced slow magnetic relaxation in a linear homotrinuclear manganese heterospin coordination compound with S = 7/2 ground state and intriguing spin density distribution†

Igor N. Shcherbakov, ORCID logo *a   Ilya I. Krotkii,a   Victoria I. Kazachkova,a   Sergey N. Lyubchenko,a   Nikolay N. Efimov,b   Arshak A. Tsaturyan ORCID logo cd  and  Vladimir A. Lazarenko ORCID logo e  

* Corresponding authors

a Southern Federal University, Chemistry Department, Rostov-On-Don, Russian Federation
E-mail: shcherbakov@sfedu.ru

b Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Moscow, Russian Federation

c Université Jean Monnet Saint-Etienne, CNRS, Institut d'Optique Graduate School, Laboratoire Hubert Curien UMR 5516, Saint-Étienne, France

d Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 Stachka Ave., Rostov-On-Don, Russia

e National Research Center “Kurchatov Institute”, Moscow, Russian Federation

Abstract

We report a first example of field-induced (HDC = 2500 Oe) slow magnetization relaxation in the homotrinuclear linear heterospin manganese coordination compound with S = 7/2 ground state, based on the bidentate 3,5-di-tert-butyl-1,2-benzoquinone-1-monooxime (HL) ligand with composition {[MnL3]Mn[MnL3]}.

Graphical abstract: Field induced slow magnetic relaxation in a linear homotrinuclear manganese heterospin coordination compound with S = 7/2 ground state and intriguing spin density distribution

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Article information

DOI
https://doi.org/10.1039/D3DT04123A
Article type
Communication
Submitted
10 Dec 2023
Accepted
01 Apr 2024
First published
01 Apr 2024

Dalton Trans., 2024,53, 6860-6864

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Field induced slow magnetic relaxation in a linear homotrinuclear manganese heterospin coordination compound with S = 7/2 ground state and intriguing spin density distribution

I. N. Shcherbakov, I. I. Krotkii, V. I. Kazachkova, S. N. Lyubchenko, N. N. Efimov, A. A. Tsaturyan and V. A. Lazarenko, Dalton Trans., 2024, 53, 6860 DOI: 10.1039/D3DT04123A

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